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Issue 26, 2012
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Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis-NHC framework

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Abstract

The reactivity of a dimethyl palladium complex supported by a dicarbene chelate (MDCMes)PdMe2 towards CO2 has been investigated. In the presence of trace H2O, this reaction yields the corresponding methyl bicarbonate complex (MDCMes)PdMe(O2COH), which goes on to give the corresponding κ2-carbonato complex upon crystallization (MDCMes)Pd(CO3). This chemistry, as well as related protonolysis by acetic acid was monitored by a combination of techniques including React-IR spectroscopy.

Graphical abstract: Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis-NHC framework

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Supplementary files

Article information


Submitted
23 Mar 2012
Accepted
18 May 2012
First published
30 May 2012

Dalton Trans., 2012,41, 7977-7983
Article type
Paper

Reaction of carbon dioxide with a palladiumalkyl complex supported by a bis-NHC framework

P. W. G. Ariyananda, G. P. A. Yap and J. Rosenthal, Dalton Trans., 2012, 41, 7977
DOI: 10.1039/C2DT30676J

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