Issue 33, 2012
From the journal:

Dalton Transactions

Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(iv)†

Fengyan Li,ab   De-Liang Long,*a   Jamie M. Cameron,a   Haralampos N. Miras,a   Chullikkattil P. Pradeep,a   Lin Xub  and  Leroy Cronin*a  

* Corresponding authors

a WestCHEM, School of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow, UK G12 8QQ
E-mail: Deliang.Long@glasgow.ac.uk, Lee.Cronin@glasgow.ac.uk
Fax: +44 (0)141 330 4888
Tel: +44 (0)141 330 6650

b Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, People's Republic of China
Fax: +86 431 85099668
Tel: +86 431 85099668

Abstract

The heteropolyvanadate cluster [(n-C4H9)4N]4[MnIVV12O34]·2CH3CN has been isolated by cation exchange from K10[(MnIVV11O32)2]·20H2O. The structural transformation has been confirmed by X-ray single crystal structure determination and cryospray ionization mass spectrometry measurements.

Graphical abstract: Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(iv)

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Article information

DOI
https://doi.org/10.1039/C2DT30627A
Article type
Communication
Submitted
03 Apr 2012
Accepted
03 May 2012
First published
04 May 2012

Dalton Trans., 2012,41, 9859-9862

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Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

F. Li, D. Long, J. M. Cameron, H. N. Miras, C. P. Pradeep, L. Xu and L. Cronin, Dalton Trans., 2012, 41, 9859 DOI: 10.1039/C2DT30627A

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