Issue 20, 2012
From the journal:

Dalton Transactions

Electrophilic attack on trinuclear titanium imido-nitrido systems†

Jorge Caballo,a   Mariano González-Moreiras,a   Miguel Mena,a   Adrián Pérez-Redondoa  and  Carlos Yélamos*a  

* Corresponding authors

a Departamento de Química Inorgánica, Universidad de Alcalá, Alcalá de Henares-Madrid, Spain
E-mail: carlos.yelamos@uah.es
Fax: +34 91 8854683
Tel: +34 91 8854898

Abstract

Alkylation of [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)] with MeOTf occurs at the imido ligands to produce the methylamido derivative [Ti3(η5-C5Me5)3(μ3-N)(μ-NH)2(μ-NHMe)(OTf)] which readily rearranges to form the methylimido complex [Ti3(η5-C5Me5)3(μ3-N)(μ-NH)(μ-NH2)(μ-NMe)(OTf)].

Graphical abstract: Electrophilic attack on trinuclear titanium imido-nitrido systems

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Article information

DOI
https://doi.org/10.1039/C2DT30486D
Article type
Communication
Submitted
29 Feb 2012
Accepted
26 Mar 2012
First published
28 Mar 2012

Dalton Trans., 2012,41, 6069-6071

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Electrophilic attack on trinuclear titanium imido-nitrido systems

J. Caballo, M. González-Moreiras, M. Mena, A. Pérez-Redondo and C. Yélamos, Dalton Trans., 2012, 41, 6069 DOI: 10.1039/C2DT30486D

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