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Issue 26, 2012
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Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(iii) species by molecular oxygen

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Abstract

A new {Fe(NO)2}10 dinitrosyl iron complex possessing a 2,9-dimethyl-1,10-phenanthroline ligand has been prepared. This complex exhibits dioxygenase activity, converting NO to nitrate (NO3) anions. During the oxygenation reaction, formation of reactive nitrating species is implicated, as shown in the effective o-nitration with a phenolic substrate.

Graphical abstract: Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(iii) species by molecular oxygen

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Article information


Submitted
23 Feb 2012
Accepted
03 Apr 2012
First published
11 Apr 2012

Dalton Trans., 2012,41, 7849-7851
Article type
Communication

Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(III) species by molecular oxygen

K. M. Skodje, P. G. Williard and E. Kim, Dalton Trans., 2012, 41, 7849
DOI: 10.1039/C2DT30443K

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