Issue 30, 2012
From the journal:

Dalton Transactions

Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl†

Rebecca C. Neu,a   Gabriel Ménarda  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry, 80 St. George St., University of Toronto, Toronto, Ontario, Canada
E-mail: dstephan@chem.utoronto.ca

Abstract

Halide exchange from the species tBu3P(CO2)B(C6F5)2Cl 1 with Me3SiOSO2CF3 gave tBu3P(CO2)B(C6F5)2(OSO2CF3) 2. Similarly, Lewis acid exchange occurs in reactions of 1 with Al(C6F5)3 and [Cp2TiMe][B(C6F5)4] affording the products, tBu3P(CO2)Al(C6F5)33 and [tBu3P(CO2)TiCp2Cl][B(C6F5)4] 4.

Graphical abstract: Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl

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Article information

DOI
https://doi.org/10.1039/C2DT30206C
Article type
Communication
Submitted
27 Jan 2012
Accepted
07 Feb 2012
First published
27 Feb 2012

Dalton Trans., 2012,41, 9016-9018

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Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl

R. C. Neu, G. Ménard and D. W. Stephan, Dalton Trans., 2012, 41, 9016 DOI: 10.1039/C2DT30206C

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