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Issue 26, 2012
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Thermally stable rare earth dialkyl complexes supported by a novel bis(phosphinimine)pyrrole ligand

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Abstract

A novel bis(phosphinimine)pyrrole based ligand (HL) and its synthesis are reported. Rare earth dialkyl complexes of the ligand, LLn(CH2SiMe3)2 (Ln = Er, Lu, Sc), have been prepared and found to exhibit high thermal stability in solution. The protio-ligand and dialkyl lanthanide complexes (Ln = Er, Lu) have been characterised by single crystal X-ray diffraction studies.

Graphical abstract: Thermally stable rare earth dialkyl complexes supported by a novel bis(phosphinimine)pyrrole ligand

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Supplementary files

Article information


Submitted
23 Dec 2011
Accepted
29 Jan 2012
First published
01 Feb 2012

Dalton Trans., 2012,41, 7873-7875
Article type
Communication

Thermally stable rare earth dialkyl complexes supported by a novel bis(phosphinimine)pyrrole ligand

K. R. D. Johnson, M. A. Hannon, J. S. Ritch and P. G. Hayes, Dalton Trans., 2012, 41, 7873
DOI: 10.1039/C2DT12485H

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