Issue 24, 2012
From the journal:

Dalton Transactions

Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution†

Atsushi Ikeda-Ohno,*ab   Satoru Tsushima,a   Christoph Hennig,a   Tsuyoshi Yaitab  and  Gert Bernharda  

* Corresponding authors

a Institute of Resource Ecology, Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstrasse 400, P.O. Box 510119, 01314 Dresden, Germany
E-mail: a.ikeda@hzdr.de, aikeda@lax.kuramae.ne.jp
Fax: +49 351 260 3553
Tel: +49 351 260 3233

b Reaction Dynamics Research Division (at SPring-8), Quantum Beam Science Directorate, Japan Atomic Energy Agency, Kouto 1-1-1, Sayo-cho, Sayo-gun, 679-5148 Hyogo-ken, Japan

Abstract

Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations.

Graphical abstract: Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2DT12406H
Article type
Communication
Submitted
13 Dec 2011
Accepted
10 Feb 2012
First published
08 Mar 2012

Dalton Trans., 2012,41, 7190-7192

Permissions

Request permissions

Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

A. Ikeda-Ohno, S. Tsushima, C. Hennig, T. Yaita and G. Bernhard, Dalton Trans., 2012, 41, 7190 DOI: 10.1039/C2DT12406H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements