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Issue 12, 2012
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Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]

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Abstract

Reaction of [Rh(CO)2{(R,R)-Ph–BPE}][BF4] 1 under 7 bar H2 provides the dihydride [Rh(H)2(CO)2{(R,R)-Ph–BPE}][BF4] 3, which reacts with the neutral hydride [Rh(H)(CO){(R,R)-Ph–BPE}] 2 arising from 3 in THF. The resulting complex is the dimeric monocationic Rh(I)–Rh(III) complex [Rh(H)2(CO)2{(R,R)-Ph–BPE}][BF4] 4.

Graphical abstract: Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]

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Publication details

The article was received on 12 Dec 2011, accepted on 27 Jan 2012 and first published on 31 Jan 2012


Article type: Communication
DOI: 10.1039/C2DT12400A
Citation: Dalton Trans., 2012,41, 3369-3373
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    Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]

    D. Crozet, D. McKay, C. Bijani, A. Gual, C. Godard, C. Claver, L. Maron, M. Urrutigoïty and P. Kalck, Dalton Trans., 2012, 41, 3369
    DOI: 10.1039/C2DT12400A

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