Issue 25, 2012
From the journal:

Dalton Transactions

Inducing hysteretic spin crossover in solution†

Paulo N. Martinho,a   Yannick Ortin,a   Brendan Gildea,a   Claudio Gandolfi,b   George McKerr,c   Barry O'Hagan,c   Martin Albrechta  and  Grace G. Morgan*a  

* Corresponding authors

a Centre for Synthesis and Chemical Biology and School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland
E-mail: grace.morgan@ucd.ie
Fax: +353 1716 1178
Tel: +353 1716 2295

b Department of Chemistry, University of Fribourg, Ch. du Musée 9, CH-1700 Fribourg, Switzerland

c School of Biomedical Sciences, University of Ulster, Cromore Road, Coleraine, UK

Abstract

A hysteretic spin transition is induced in a solution assembly of a mononuclear FeIII amphiphilic complex which exhibits only gradual spin crossover in the solid state. The hysteretic behavior is dependent on dynamic solution assembly and removal of solvent causes reversion to the original bulk solid magnetic response.

Graphical abstract: Inducing hysteretic spin crossover in solution

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Article information

DOI
https://doi.org/10.1039/C2DT12036D
Article type
Communication
Submitted
26 Oct 2011
Accepted
16 Mar 2012
First published
12 Apr 2012

Dalton Trans., 2012,41, 7461-7463

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Inducing hysteretic spin crossover in solution

P. N. Martinho, Y. Ortin, B. Gildea, C. Gandolfi, G. McKerr, B. O'Hagan, M. Albrecht and G. G. Morgan, Dalton Trans., 2012, 41, 7461 DOI: 10.1039/C2DT12036D

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