Issue 5, 2012
From the journal:

Dalton Transactions

Self-adaptation of manganese–chloride arrangement toward high spin Mn5(μ-Cl)4 cluster-based metal–organic framework with S = 15/2†

Shao-Hsuan Lin,ab   Chen-I Yang,a   Ting-Shen Kuo,b   Ming-Hsi Chiang,a   Kung-Chung Hsu*b  and  Kuang-Lieh Lu*a  

* Corresponding authors

a Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan
E-mail: lu@chem.sinica.edu.tw
Fax: 886-2-27831237
Tel: 886-2-27898518

b Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan

Abstract

The self-adaptation of manganese–chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me3-TBzIm) afforded a rare 3D metal–organic framework, [Mn5Cl10(Me3-TBzIm)4]n (1) showing a high spin ground state with S = 15/2.

Graphical abstract: Self-adaptation of manganese–chloride arrangement toward high spin Mn5(μ-Cl)4 cluster-based metal–organic framework with S = 15/2

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Article information

DOI
https://doi.org/10.1039/C2DT11760F
Article type
Communication
Submitted
16 Sep 2011
Accepted
30 Nov 2011
First published
20 Dec 2011

Dalton Trans., 2012,41, 1448-1450

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Self-adaptation of manganese–chloride arrangement toward high spin Mn5(μ-Cl)4 cluster-based metal–organic framework with S = 15/2

S. Lin, C. Yang, T. Kuo, M. Chiang, K. Hsu and K. Lu, Dalton Trans., 2012, 41, 1448 DOI: 10.1039/C2DT11760F

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