A novel 2D → 3D {Co6PW9}-based framework extended by semi-rigid bis(triazole) ligand

Xiuli Wang; Xiaojing Liu; Aixiang Tian; Jun Ying; Hongyan Lin; Guocheng Liu; Qiang Gao

doi:10.1039/C2DT00039C

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A novel 2D → 3D {Co₆PW₉}-based framework extended by semi-rigid bis(triazole) ligand†

Xiuli Wang,*^a Xiaojing Liu,^a Aixiang Tian,^a Jun Ying,^a Hongyan Lin,^a Guocheng Liu^a and Qiang Gao^a

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* Corresponding authors

^a Department of Chemistry, Bohai University, Jinzhou, P.R. China
E-mail: wangxiuli@bhu.edu.cn
Fax: +86-416-3400158
Tel: +86-416-3400158

Abstract

The building blocks {Co₆PW₉} converging lacunary polyoxometalates and high-nuclear {Co₆} clusters are further linked by semi-rigid bis(triazole) ligands to construct a 2D → 3D framework under hydrothermal conditions, [Co₆(μ₃-OH)₃(H₂O)₉L(PW₉O₃₄)] (1) (L = 4,4′-bis(1,2,4-triazol-1-ylmethyl)biphenyl).

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Article information

DOI: https://doi.org/10.1039/C2DT00039C
Article type: Communication
Submitted: 06 Jan 2012
Accepted: 20 Apr 2012
First published: 23 Apr 2012

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Dalton Trans., 2012,41, 9587-9589

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A novel 2D → 3D {Co₆PW₉}-based framework extended by semi-rigid bis(triazole) ligand

X. Wang, X. Liu, A. Tian, J. Ying, H. Lin, G. Liu and Q. Gao, Dalton Trans., 2012, 41, 9587 DOI: 10.1039/C2DT00039C

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Dalton Transactions