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Issue 26, 2012
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Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(i)

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Abstract

Phosphinoamide ligands have been utilized to link a CoI center to a Nb or Ta imido fragment. The resulting heterobimetallic complexes, ICo(Ph2PNiPr)3M[double bond, length as m-dash]NtBu, have weakened dative metal–metal interactions as a result of the strongly donating imido ligand. These complexes can be reduced by 2 electrons to generate dinitrogen-bound complexes.

Graphical abstract: Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(i)

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Article information


Submitted
05 Jan 2012
Accepted
24 Feb 2012
First published
28 Feb 2012

Dalton Trans., 2012,41, 8111-8115
Article type
Paper

Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(I)

D. A. Evers, A. H. Bluestein, B. M. Foxman and C. M. Thomas, Dalton Trans., 2012, 41, 8111
DOI: 10.1039/C2DT00034B

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