“Squaring the clusters”: a MnIII4NiII4 molecular square from nickel(II)-induced structural transformation of a MnII/III/IV12 cage

Dimitris I. Alexandropoulos; Manolis J. Manos; Constantina Papatriantafyllopoulou; Shreya Mukherjee; Anastasios J. Tasiopoulos; Spyros P. Perlepes; George Christou; Theocharis C. Stamatatos

doi:10.1039/C2DT00030J

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“Squaring the clusters”: a Mn^III₄Ni^II₄ molecular square from nickel(ii)-induced structural transformation of a Mn^II/III/IV₁₂ cage†

Dimitris I. Alexandropoulos,^a Manolis J. Manos,^b Constantina Papatriantafyllopoulou,^c Shreya Mukherjee,^c Anastasios J. Tasiopoulos,^b Spyros P. Perlepes,^a George Christou*^c and Theocharis C. Stamatatos*^ad

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* Corresponding authors

^a Department of Chemistry, University of Patras, 26504 Patras, Greece
E-mail: thstama@chemistry.upatras.gr
Tel: +30-2610-996020

^b Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus

^c Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA

^d Department of General and Inorganic Chemistry, Faculty of Chemistry, Aristotle University of Thessaloniki, P.O. Box 135, 54124 Thessaloniki, Greece

Abstract

A Mn^III₄Ni^II₄ molecular square exhibiting slow magnetization relaxation has been prepared from the reaction of a Mn^II₄Mn^III₆Mn^IV₂ cluster and a simple Ni^II source.

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Article information

DOI: https://doi.org/10.1039/C2DT00030J
Article type: Communication
Submitted: 05 Jan 2012
Accepted: 05 Mar 2012
First published: 06 Mar 2012

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Dalton Trans., 2012,41, 4744-4747

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“Squaring the clusters”: a Mn^III₄Ni^II₄ molecular square from nickel(II)-induced structural transformation of a Mn^II/III/IV₁₂ cage

D. I. Alexandropoulos, M. J. Manos, C. Papatriantafyllopoulou, S. Mukherjee, A. J. Tasiopoulos, S. P. Perlepes, G. Christou and T. C. Stamatatos, Dalton Trans., 2012, 41, 4744 DOI: 10.1039/C2DT00030J

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