Issue 2, 2012
From the journal:

Dalton Transactions

Oxidation and coupling of β-diketiminate ligand in lanthanide complexes: Novel eight-nuclear lanthanide clusters with μ-, μ3-Cl, and μ4-O bridge†

Jie Zhang,*a   Zhengxing Zhang,a   Zhenxia Chena  and  Xigeng Zhou*a  

* Corresponding authors

a Department of Chemistry, Fudan University, Shanghai, China
E-mail: zhangjie@fudan.edu.cn
Fax: +86 21 65641740
Tel: +86 21 65643885

Abstract

Two novel eight-nuclear lanthanide oxide and chloride clusters Ln8(μ-η2-L4)2(μ3-Cl)4(μ-Cl)10(μ4-O)3(THF)8 (Ln = Er(3), Dy(4); L4 = [OC{(Me)CN-2,6-iPrC6H3}2]2−) have been synthesized by the reaction of β-diketiminate rare-earth metal chlorides with oxygen, providing a new oxidation and coupling reaction of the β-diketiminate ligand.

Graphical abstract: Oxidation and coupling of β-diketiminate ligand in lanthanide complexes: Novel eight-nuclear lanthanide clusters with μ-, μ3-Cl, and μ4-O bridge

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Article information

DOI
https://doi.org/10.1039/C1DT11383F
Article type
Communication
Submitted
22 Jul 2011
Accepted
19 Oct 2011
First published
14 Nov 2011

Dalton Trans., 2012,41, 357-359

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Oxidation and coupling of β-diketiminate ligand in lanthanide complexes: Novel eight-nuclear lanthanide clusters with μ-, μ3-Cl, and μ4-O bridge

J. Zhang, Z. Zhang, Z. Chen and X. Zhou, Dalton Trans., 2012, 41, 357 DOI: 10.1039/C1DT11383F

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