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Issue 3, 2012
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1,2-Benzoquinones in Diels–Alder reactions, dipolar cycloadditions, nucleophilic additions, multicomponent reactions and more

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Abstract

A brief account of the recent developments in the chemistry of 1,2-benzoquinones is presented in this tutorial review. The title compounds exhibit commendable versatility in both Diels–Alder and dipolar cycloaddition reactions. They have also been employed as electrophilic reaction partners in nucleophile-triggered catalytic processes and related multicomponent reactions. These, along with other reactions described here, lead to the synthesis of densely functionalised carbocyclic and heterocyclic frameworks that are otherwise difficult to access.

Graphical abstract: 1,2-Benzoquinones in Diels–Alder reactions, dipolar cycloadditions, nucleophilic additions, multicomponent reactions and more

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Publication details

The article was received on 11 Jul 2011 and first published on 21 Sep 2011


Article type: Tutorial Review
DOI: 10.1039/C1CS15186J
Citation: Chem. Soc. Rev., 2012,41, 1050-1059

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    1,2-Benzoquinones in Diels–Alder reactions, dipolar cycloadditions, nucleophilic additions, multicomponent reactions and more

    V. Nair, R. S. Menon, A. T. Biju and K. G. Abhilash, Chem. Soc. Rev., 2012, 41, 1050
    DOI: 10.1039/C1CS15186J

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