Issue 32, 2012

Resonance Raman studies of excited state structural displacements of conjugated polymers in donor/acceptor charge transfer complexes

Abstract

Resonance Raman spectra of poly(2-methoxy-5-(3′-7′-dimethyloctyloxy)-1,4-phenylenevinylene) (MDMO-PPV) and small molecule acceptor blend charge transfer (CT) complexes reveal long and detailed progressions of overtone and combination bands. These features are sensitive to the specific MDMO-PPV/acceptor interactions and enable quantitative calculations of vibrational mode specific displacements of the polymer CT complex.

Graphical abstract: Resonance Raman studies of excited state structural displacements of conjugated polymers in donor/acceptor charge transfer complexes

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
28 May 2012
Accepted
29 Jun 2012
First published
02 Jul 2012

Phys. Chem. Chem. Phys., 2012,14, 11273-11276

Resonance Raman studies of excited state structural displacements of conjugated polymers in donor/acceptor charge transfer complexes

A. J. Wise and J. K. Grey, Phys. Chem. Chem. Phys., 2012, 14, 11273 DOI: 10.1039/C2CP41748K

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