Tuning microcavities in thermally rearranged polymer membranes for CO2 capture

Abstract

Microporous materials have a great importance in catalysis, delivery, storage and separation in terms of their performance and efficiency. Most microporous materials are comprised of inorganic frameworks, while thermally rearranged (TR) polymers are a microporous organic polymer which is tuned to optimize the cavity sizes and distribution for difficult separation applications. The sub-nano sized microcavities are controlled by in situ thermal treatment conditions which have been investigated by positron annihilation lifetime spectroscopy (PALS). The size and relative number of cavities increased from room temperature to 230 °C resulting in improvements in both permeabilities and selectivities for H₂/CO₂ separation due to the significant increase of gas diffusion and decrease of CO₂ solubility. The highest performance of the well-tuned TR-polymer membrane was 206 Barrer for H₂ permeability and 6.2 of H₂/CO₂ selectivity, exceeding the polymeric upper bound for gas separation membranes.