Issue 18, 2012

Transmetalations in two metal–organic frameworks with different framework flexibilities: Kinetics and core–shell heterostructure

Abstract

While only a partially transmetalated network was observed in a rigid metal–organic framework (MOF), not only a completely transmetalated isostructural network but also a partially transmetalated core–shell heterostructural network could be obtained in a flexible MOF by controlling the reaction conditions.

Graphical abstract: Transmetalations in two metal–organic frameworks with different framework flexibilities: Kinetics and core–shell heterostructure

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2012
Accepted
16 Jul 2012
First published
02 Aug 2012

CrystEngComm, 2012,14, 5753-5756

Transmetalations in two metal–organic frameworks with different framework flexibilities: Kinetics and core–shell heterostructure

X. Song, S. Jeong, D. Kim and M. S. Lah, CrystEngComm, 2012, 14, 5753 DOI: 10.1039/C2CE26115D

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