Issue 20, 2012
From the journal:

CrystEngComm

Conglomerate crystallization, chiral recognition and spin-crossover in a host–guest complex consisting of FeIII complexes (host) and [Cr(ox)3]3− (guest)†‡

Yukinari Sunatsuki,*a   Sho Miyahara,a   Yuu Sasaki,a   Takayoshi Suzuki,a   Masaaki Kojimaa  and  Naohide Matsumotob  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Tsushima-naka 3-1-1, Kita-ku, Okayama, Japan
E-mail: sunatuki@cc.okayama-u.ac.jp
Fax: (+81)86-251-7833

b Department of Chemistry, Faculty of Science, Kumamoto University, Kurokami 2-39-1, Chūō-ku, Kumamoto, Japan

Abstract

A host–guest complex, [FeIII(H3L)][FeIII(L)][CrIII(ox)3]·3H2O (1), where H3L and L3− serve as hexadentate ligands, was prepared. In 1, three properties are united: the homochiral assembly of chiral [FeIII(H3L)]3+ and [FeIII(L)] into a conglomerate structure, the chiral recognition of the host FeIII assembly to the guest [CrIII(ox)3]3− and the spin-crossover of [FeIII(H3L)]3+.

Graphical abstract: Conglomerate crystallization, chiral recognition and spin-crossover in a host–guest complex consisting of FeIII complexes (host) and [Cr(ox)3]3− (guest)

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Article information

DOI
https://doi.org/10.1039/C2CE25612F
Article type
Communication
Submitted
20 Apr 2012
Accepted
18 Jun 2012
First published
22 Jun 2012

CrystEngComm, 2012,14, 6377-6380

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Conglomerate crystallization, chiral recognition and spin-crossover in a host–guest complex consisting of FeIII complexes (host) and [Cr(ox)3]3− (guest)

Y. Sunatsuki, S. Miyahara, Y. Sasaki, T. Suzuki, M. Kojima and N. Matsumoto, CrystEngComm, 2012, 14, 6377 DOI: 10.1039/C2CE25612F

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