Issue 12, 2012
From the journal:

CrystEngComm

Highly rigid and stable porous Cu(i) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation†

Sudip Mohapatra,a   Hiroshi Sato,bc   Ryotaro Matsuda,bc   Susumu Kitagawabc  and  Tapas Kumar Maji*a  

* Corresponding authors

a Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India
E-mail: tmaji@jncasr.ac.in
Fax: (+91) 80 2208 2766
Tel: (+91) 80 2208 2826

b The Institute for Integrated Cell-Material Sciences, Kyoto University, Kyoto Research Park Bldg#3, 93 Chudoji-Awatacho, Shimogyo-ku, Kyoto, Japan

c Kitagawa Integrated Pore Project, ERATO, JST, Kyoto 600-8815, Japan

Abstract

A simple room temperature reaction of Cu(NO3)2, and 2,3-pyrazinedicarboxylic acid (H2pyzdc) in the presence of dihydroxyfumaric acid (DHFA) resulted in the formation of a highly stable 3D Cu(I) coordination polymer, {[Cu2(pyzdc)]·0.83H2O}n where DHFA acts as a reducing agent. It possesses a 1D water filled channel along the crystallographic c direction and the framework shows reversible single-crystal-to-single-crystal structural transformation upon dehydration and rehydration.

Graphical abstract: Highly rigid and stable porous Cu(i) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation

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Article information

DOI
https://doi.org/10.1039/C2CE06701C
Article type
Communication
Submitted
19 Dec 2011
Accepted
21 Mar 2012
First published
21 Mar 2012

CrystEngComm, 2012,14, 4153-4156

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Highly rigid and stable porous Cu(I) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation

S. Mohapatra, H. Sato, R. Matsuda, S. Kitagawa and T. K. Maji, CrystEngComm, 2012, 14, 4153 DOI: 10.1039/C2CE06701C

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