Issue 1, 2012
From the journal:

CrystEngComm

Axially chiral metal–organic frameworks produced from spontaneous resolution with an achiral pyridyl dicarboxylate ligand†

Xin Tan,a   Jixian Zhan,a   Jianyong Zhang,*a   Long Jiang,a   Mei Pana  and  Cheng-Yong Sua  

* Corresponding authors

a KLGHEI of Environment and Energy Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, China
E-mail: zhjyong@mail.sysu.edu.cn

Abstract

Three-dimensional chiral (10,3)-c MOFs are generated via symmetry breaking from achiral precursors, 5-(pyridine-3-yl)isophthalic acid and M2+ (M = Cd, Zn, Mn), and chiral transmission from molecular axially chiral conformations to framework chirality is established.

Graphical abstract: Axially chiral metal–organic frameworks produced from spontaneous resolution with an achiral pyridyl dicarboxylate ligand

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Article information

DOI
https://doi.org/10.1039/C1CE05995E
Article type
Communication
Submitted
03 Aug 2011
Accepted
13 Oct 2011
First published
03 Nov 2011

CrystEngComm, 2012,14, 63-66

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Axially chiral metal–organic frameworks produced from spontaneous resolution with an achiral pyridyl dicarboxylate ligand

X. Tan, J. Zhan, J. Zhang, L. Jiang, M. Pan and C. Su, CrystEngComm, 2012, 14, 63 DOI: 10.1039/C1CE05995E

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