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Issue 94, 2012
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Hysteretic carbon dioxide sorption in a novel copper(II)-indazole-carboxylate porous coordination polymer

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Abstract

The synthesis, structural and gas sorption studies of a porous Cu(II) coordination polymer featuring 1H-indazole-5-carboxylic acid (H2L) are presented. [Cu(HL)2] is a thermally and hydrolytically robust 4-connected 3D coordination polymer of NbO topology and is replete with 1D channels that permit selective and hysteretic sorption of CO2.

Graphical abstract: Hysteretic carbon dioxide sorption in a novel copper(ii)-indazole-carboxylate porous coordination polymer

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Publication details

The article was received on 30 Jul 2012, accepted on 12 Oct 2012 and first published on 18 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC37453F
Chem. Commun., 2012,48, 11558-11560

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    Hysteretic carbon dioxide sorption in a novel copper(II)-indazole-carboxylate porous coordination polymer

    C. S. Hawes, R. Babarao, M. R. Hill, K. F. White, B. F. Abrahams and P. E. Kruger, Chem. Commun., 2012, 48, 11558
    DOI: 10.1039/C2CC37453F

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