Issue 99, 2012
From the journal:

Chemical Communications

Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids†

Tigran S. Kurtikyan,*a   Vardan A. Hayrapetyan,a   Garik G. Martirosyan,a   Robert K. Ghazaryan,a   Alexei V. Iretskii,b   Hailiang Zhao,c   Kristine Pierloot*c  and  Peter C. Ford*d  

* Corresponding authors

a Molecule Structure Research Center (MSRC), National Academy of Sciences, Yerevan, Armenia
E-mail: kurto@netsys.am
Fax: +374 10 282267
Tel: +374 10 287423

b Department of Chemistry, Lake Superior State University, Sault Sainte Marie, MI, USA

c Department of Chemistry, University of Leuven, B-3001 Heverlee, Belgium
E-mail: Kristin.Pierloot@chem.kuleuven.be
Fax: +32-16-327992

d Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA, USA
E-mail: ford@chem.ucsb.edu
Fax: +1 805-8934120
Tel: +1 805-8932443

Abstract

Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn–N–O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.

Graphical abstract: Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids

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Article information

DOI
https://doi.org/10.1039/C2CC37337H
Article type
Communication
Submitted
08 Oct 2012
Accepted
01 Nov 2012
First published
02 Nov 2012

Chem. Commun., 2012,48, 12088-12090

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Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids

T. S. Kurtikyan, V. A. Hayrapetyan, G. G. Martirosyan, R. K. Ghazaryan, A. V. Iretskii, H. Zhao, K. Pierloot and P. C. Ford, Chem. Commun., 2012, 48, 12088 DOI: 10.1039/C2CC37337H

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