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Issue 99, 2012
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Bay-substituted perylene bisimide dye with an undistorted planar scaffold and outstanding solid state fluorescence properties

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Abstract

Single crystal X-ray analysis reveals a flat perylene π-scaffold for a perylene bisimide bearing bulky 2,6-diphenylphenoxy substituents at the 1,7 bay positions. The flat structure provides sharp vibronic progressions in the absorption and fluorescence spectra, the sterical shielding outstanding fluorescence quantum yields in the solid state.

Graphical abstract: Bay-substituted perylene bisimide dye with an undistorted planar scaffold and outstanding solid state fluorescence properties

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Supplementary files

Article information


Submitted
14 Sep 2012
Accepted
12 Oct 2012
First published
29 Oct 2012

Chem. Commun., 2012,48, 12050-12052
Article type
Communication

Bay-substituted perylene bisimide dye with an undistorted planar scaffold and outstanding solid state fluorescence properties

M. Lin, Á. J. Jiménez, C. Burschka and F. Würthner, Chem. Commun., 2012, 48, 12050 DOI: 10.1039/C2CC36719J

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