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A novel semiconducting benzothiadiazole (BTZ)–thiophene (T) co-oligomer having an unprecedented BTZ–T alternated motif has been synthesized and self-assembled into micrometer sized fibers by simple solution processing. The electrical properties of these low-dimensional architectures have been characterized by integrating them in an organic field-effect transistor.

Graphical abstract: Self-assembly and electrical properties of a novel heptameric thiophene–benzothiadiazole based architectures

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