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Issue 84, 2012
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σ-Donor–σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt0 and PbII fragments

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Abstract

Mono- and diplatinum plumbylene complexes are prepared in which the bonding comprises synergic σ donation between the Pt and Pb atoms. The bonding distinguishes the complexes from both the classical Fischer carbene bonding model and M→Pb dative-only bonding. The Pt–Pb bond of the monoplatinum complex is stable, while the diplatinum complex reversibly loses one Pt fragment.

Graphical abstract: σ-Donor–σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt0 and Pbii fragments

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Publication details

The article was received on 09 Aug 2012, accepted on 04 Sep 2012 and first published on 05 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC35777A
Citation: Chem. Commun., 2012,48, 10410-10412
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    σ-Donor–σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt0 and PbII fragments

    H. Braunschweig, A. Damme, R. D. Dewhurst, F. Hupp, J. O. C. Jimenez-Halla and K. Radacki, Chem. Commun., 2012, 48, 10410
    DOI: 10.1039/C2CC35777A

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