Jump to main content
Jump to site search

Issue 92, 2012
Previous Article Next Article

Making practical use of the pseudo-element concept: an efficient way to ternary intermetalloid clusters by an isoelectronic Pb–Bi combination

Author affiliations

Abstract

Syntheses of [K([2.2.2]crypt)]+ salts of binary Pb–Bi Zintl anions and their reaction with ZnPh2 or Ni(cod)2, yielding ternary intermetalloid Ni–Pb–Bi or Zn–Pb–Bi clusters, proved the use of binary precursors with fully isoelectronic atoms as an efficient and thus valuable synthetic approach to this class of clusters. 207Pb NMR and ESI mass spectra provided insight into the solution behavior of the binary or ternary cages.

Graphical abstract: Making practical use of the pseudo-element concept: an efficient way to ternary intermetalloid clusters by an isoelectronic Pb−–Bi combination

Back to tab navigation

Supplementary files

Article information


Submitted
23 Jul 2012
Accepted
22 Aug 2012
First published
24 Aug 2012

Chem. Commun., 2012,48, 11295-11297
Article type
Communication

Making practical use of the pseudo-element concept: an efficient way to ternary intermetalloid clusters by an isoelectronic Pb–Bi combination

R. Ababei, J. Heine, M. Hołyńska, G. Thiele, B. Weinert, X. Xie, F. Weigend and S. Dehnen, Chem. Commun., 2012, 48, 11295 DOI: 10.1039/C2CC35318K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.


Social activity

Search articles by author

Spotlight

Advertisements