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Issue 76, 2012
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Enantioselective alkylation of β-keto phosphonates by direct use of diaryl methanols as electrophiles

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Abstract

Enantioselective alkylation of β-keto phosphonates with diaryl methanols in the presence of catalytic amounts of copper(II) trifluoromethanesulfonate and an optically active ligand gives the corresponding alkylated products in good to high yields with a high enantioselectivity.

Graphical abstract: Enantioselective alkylation of β-keto phosphonates by direct use of diaryl methanols as electrophiles

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Article information


Submitted
21 Jul 2012
Accepted
05 Aug 2012
First published
07 Aug 2012

Chem. Commun., 2012,48, 9528-9530
Article type
Communication

Enantioselective alkylation of β-keto phosphonates by direct use of diaryl methanols as electrophiles

M. Shibata, M. Ikeda, K. Motoyama, Y. Miyake and Y. Nishibayashi, Chem. Commun., 2012, 48, 9528
DOI: 10.1039/C2CC35262A

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