Issue 82, 2012
From the journal:

Chemical Communications

A ladder type iron(ii) coordination polymer with cooperative spin transition†

Wolfgang Bauer,a   Stephan Schlampa  and  Birgit Weber*a  

* Corresponding authors

a Inorganic Chemistry II, Universität Bayreuth, Universitätsstraβe 30, NW 1, 95440 Bayreuth, Germany
E-mail: weber@uni-bayreuth.de
Fax: +49-92155-2157
Tel: +49-92155-2555

Abstract

Ladder type 1D coordination polymers were synthesised with the aim to improve the spin crossover properties of the iron(II) complexes following the concepts of crystal engineering. A wide hysteresis loop (34 K) was observed if rigid linkers were used. The first X-ray structure for a 1D iron(II) ladder is reported.

Graphical abstract: A ladder type iron(ii) coordination polymer with cooperative spin transition

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Article information

DOI
https://doi.org/10.1039/C2CC35109A
Article type
Communication
Submitted
17 Jul 2012
Accepted
26 Aug 2012
First published
28 Aug 2012

Chem. Commun., 2012,48, 10222-10224

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A ladder type iron(II) coordination polymer with cooperative spin transition

W. Bauer, S. Schlamp and B. Weber, Chem. Commun., 2012, 48, 10222 DOI: 10.1039/C2CC35109A

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