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A series of new 2,3,5-triaryl-substituted oxazolium and thiazolium salts are readily prepared by a Tf2O-mediated intramolecular cyclisation and their use as precursors for the synthesis of novel oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes has been developed.

Graphical abstract: Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties

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