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Issue 78, 2012
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Plutonium(iv) complexation by diglycolamideligands—coordination chemistry insight into TODGA-based actinide separations

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Abstract

Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1 : 3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere.

Graphical abstract: Plutonium(iv) complexation by diglycolamide ligands—coordination chemistry insight into TODGA-based actinide separations

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Supplementary files

Article information


Submitted
11 Jul 2012
Accepted
10 Aug 2012
First published
23 Aug 2012

Chem. Commun., 2012,48, 9732-9734
Article type
Communication

Plutonium(IV) complexation by diglycolamide ligands—coordination chemistry insight into TODGA-based actinide separations

S. D. Reilly, A. J. Gaunt, B. L. Scott, G. Modolo, M. Iqbal, W. Verboom and M. J. Sarsfield, Chem. Commun., 2012, 48, 9732
DOI: 10.1039/C2CC34967A

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