Issue 76, 2012
From the journal:

Chemical Communications

A new Al-MOF based on a unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behaviour†‡

Helge Reinsch,a   Bartosz Marszałek,b   Julia Wack,c   Jürgen Senker,c   Barbara Gilb  and  Norbert Stock*a  

* Corresponding authors

a Institute of Inorganic Chemistry, Christian-Albrechts-Universität Kiel, Max-Eyth-Straße 2, 24118 Kiel, Germany
E-mail: stock@ac.uni-kiel.de

b Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Kraków, Poland

c Inorganic Chemistry I, Universität Bayreuth, Universitätsstaße 30, 95447 Bayreuth, Germany

Abstract

The new Al-based metal–organic framework [Al13(OH)27(H2O)6(BDC-NH2)3Cl6(C3H7OH)6] denoted CAU-6 (CAU = Christian-Albrechts-Universität) was solvothermally synthesized in 2-propanol and was thoroughly characterized. The framework structure exhibits a unique column-shaped inorganic building unit, which is based on stacked, corner-sharing Al13-clusters. The compound exhibits unprecedented hydrophilicity for metal–organic frameworks.

Graphical abstract: A new Al-MOF based on a unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behaviour

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Article information

DOI
https://doi.org/10.1039/C2CC34909D
Article type
Communication
Submitted
09 Jul 2012
Accepted
07 Aug 2012
First published
08 Aug 2012

Chem. Commun., 2012,48, 9486-9488

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A new Al-MOF based on a unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behaviour

H. Reinsch, B. Marszałek, J. Wack, J. Senker, B. Gil and N. Stock, Chem. Commun., 2012, 48, 9486 DOI: 10.1039/C2CC34909D

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