Issue 77, 2012
From the journal:

Chemical Communications

Synthesis of novel nonlinear optical chromophore to achieve ultrahigh electro-optic activity†

Jieyun Wu,ab   Shuhui Bo,b   Jialei Liu,b   Tingting Zhou,ab   Hongyan Xiao,b   Ling Qiu,b   Zhen Zhenb  and  Xinhou Liu*b  

* Corresponding authors

a Graduated University of Chinese Academy of Sciences, Beijing, China

b Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technique Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, China
E-mail: xinhouliu@yahoo.cn

Abstract

A new diene-conjugated chromophore WJ1 was synthesized with high yield of 36% through an H-bonding induced Vilsmeier reaction. By simple guest-host doping, a large electro-optic efficiency of 337 pm V−1 at 1310 nm and excellent temporal stability at 75 °C have been achieved in poled films of WJ1/APC with a high loading density of 40 wt%.

Graphical abstract: Synthesis of novel nonlinear optical chromophore to achieve ultrahigh electro-optic activity

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC34747D
Article type
Communication
Submitted
03 Jul 2012
Accepted
25 Jul 2012
First published
25 Jul 2012

Chem. Commun., 2012,48, 9637-9639

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Synthesis of novel nonlinear optical chromophore to achieve ultrahigh electro-optic activity

J. Wu, S. Bo, J. Liu, T. Zhou, H. Xiao, L. Qiu, Z. Zhen and X. Liu, Chem. Commun., 2012, 48, 9637 DOI: 10.1039/C2CC34747D

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