Issue 72, 2012
From the journal:

Chemical Communications

Lycopalhine A, a novel sterically congested Lycopodiumalkaloid with an unprecedented skeleton from Palhinhaea cernua†

Liao-Bin Dong,ab   Jing Yang,c   Juan He,a   Huai-Rong Luo,a   Xing-De Wu,a   Xu Deng,a   Li-Yan Peng,a   Xiao Chenga  and  Qin-Shi Zhao*a  

* Corresponding authors

a State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201, P. R. China
E-mail: qinshizhao@mail.kib.ac.cn
Fax: +86-871-5215783
Tel: +86-871-5223058

b Graduate University of the Chinese Academy of Sciences, Beijing 100049, P. R. China

c Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, P. R. China

Abstract

A novel sterically congested Lycopodium alkaloid named lycopalhine A (1) that possesses a fused hexacyclic (5/5/5/6/6/6) ring system comprising a 5,9-diaza-tricyclo[6.2.1.04,9]undecane moiety and a tricyclo[5.2.1.04,8]decane moiety was isolated from Palhinhaea cernua L. The structure and absolute configuration were determined by spectroscopic and computational methods.

Graphical abstract: Lycopalhine A, a novel sterically congested Lycopodium alkaloid with an unprecedented skeleton from Palhinhaea cernua

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Article information

DOI
https://doi.org/10.1039/C2CC34676A
Article type
Communication
Submitted
29 Jun 2012
Accepted
20 Jul 2012
First published
20 Jul 2012

Chem. Commun., 2012,48, 9038-9040

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Lycopalhine A, a novel sterically congested Lycopodium alkaloid with an unprecedented skeleton from Palhinhaea cernua

L. Dong, J. Yang, J. He, H. Luo, X. Wu, X. Deng, L. Peng, X. Cheng and Q. Zhao, Chem. Commun., 2012, 48, 9038 DOI: 10.1039/C2CC34676A

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