Issue 85, 2012
From the journal:

Chemical Communications

Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O2†

Yu Hea  and  Christian R. Goldsmith*a  

* Corresponding authors

a Auburn University, Department of Chemistry and Biochemistry, Auburn, USA
E-mail: crgoldsmith@auburn.edu

Abstract

A non-heme iron complex catalyses the oxidation of allylic, benzylic, and aliphatic C–H bonds by O2. During this reactivity, a ferric hydroperoxide species is observed. The kinetic analysis of this complex's formation may suggest a ferric superoxo species as the initial metal-based oxidant.

Graphical abstract: Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O2

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Article information

DOI
https://doi.org/10.1039/C2CC34634F
Article type
Communication
Submitted
28 Jun 2012
Accepted
06 Sep 2012
First published
19 Sep 2012

Chem. Commun., 2012,48, 10532-10534

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Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O2

Y. He and C. R. Goldsmith, Chem. Commun., 2012, 48, 10532 DOI: 10.1039/C2CC34634F

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