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Issue 80, 2012
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A versatile metal–organic framework for carbon dioxide capture and cooperative catalysis

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Abstract

A multi-functional MOF PCN-124 was constructed from Cu paddlewheel motifs and a judiciously designed novel ligand bearing carboxylate, pyridine, and amide groups. PCN-124 exhibits selective adsorption of CO2 over CH4 and excellent catalytic activity in a tandem one-pot deacetalization–Knoevenagel condensation reaction as a cooperative catalyst.

Graphical abstract: A versatile metal–organic framework for carbon dioxide capture and cooperative catalysis

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Article information


Submitted
28 Jun 2012
Accepted
21 Aug 2012
First published
22 Aug 2012

Chem. Commun., 2012,48, 9995-9997
Article type
Communication

A versatile metal–organic framework for carbon dioxide capture and cooperative catalysis

J. Park, J. Li, Y. Chen, J. Yu, A. A. Yakovenko, Z. U. Wang, L. Sun, P. B. Balbuena and H. Zhou, Chem. Commun., 2012, 48, 9995
DOI: 10.1039/C2CC34622B

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