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Issue 85, 2012
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Assessing the adsorption selectivity of linker functionalized, moisture-stable metal–organic framework thin films by means of an environment-controlled quartz crystal microbalance

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Abstract

The stepwise thin film deposition of the robust, hydrophobic [Zn4O(dmcapz)3]n (dmcapz = 3,5-dimethyl-4-carboxy-pyrazolato) is reported. The adsorption of small organic probe molecules, including alkanols, toluene, aniline and xylenes, was monitored by an environment-controlled quartz crystal microbalance setup. The adsorption selectivity was tuned by introducing alkyl side chains in the dmcapz linker.

Graphical abstract: Assessing the adsorption selectivity of linker functionalized, moisture-stable metal–organic framework thin films by means of an environment-controlled quartz crystal microbalance

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Article information


Submitted
27 Jun 2012
Accepted
05 Sep 2012
First published
06 Sep 2012

Chem. Commun., 2012,48, 10493-10495
Article type
Communication

Assessing the adsorption selectivity of linker functionalized, moisture-stable metal–organic framework thin films by means of an environment-controlled quartz crystal microbalance

A. Bétard, S. Wannapaiboon and R. A. Fischer, Chem. Commun., 2012, 48, 10493
DOI: 10.1039/C2CC34608G

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