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Issue 67, 2012
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Zr(iv) and Hf(iv) based metal–organic frameworks with reo-topology

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Abstract

Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.

Graphical abstract: Zr(iv) and Hf(iv) based metal–organic frameworks with reo-topology

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Submitted
13 Jun 2012
Accepted
04 Jul 2012
First published
06 Jul 2012

Chem. Commun., 2012,48, 8407-8409
Article type
Communication

Zr(IV) and Hf(IV) based metal–organic frameworks with reo-topology

V. Bon, V. Senkovskyy, I. Senkovska and S. Kaskel, Chem. Commun., 2012, 48, 8407
DOI: 10.1039/C2CC34246D

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