A general ‘one-pot’ method for determining relative rates of reaction in complex mixtures has been established using free energy relationships to demonstrate its utility. Competition experiments involving as many as seven species gave relative rate constants that are in good agreement to those obtained from individual kinetic analyses.
H. M. Yau, A. K. Croft and J. B. Harper, Chem. Commun., 2012, 48, 8937 DOI: 10.1039/C2CC34074G
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