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Issue 67, 2012

A 32 vertex polyhedron via supramolecular assembly of silanedithiolate silanolate units

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Abstract

A high yield synthesis of the first silanedithiolate silanolate is reported which spontaneously assembles forming an inorganic rugby ball shaped 32 vertex polyhedral cluster stabilized by sterically demanding 2,6-dimesitylphenyl substituents and two LiCl units.

Graphical abstract: A 32 vertex polyhedron via supramolecular assembly of silanedithiolate silanolate units

Supplementary files

Article information


Submitted
30 May 2012
Accepted
28 Jun 2012
First published
29 Jun 2012

Chem. Commun., 2012,48, 8398-8400
Article type
Communication

A 32 vertex polyhedron via supramolecular assembly of silanedithiolate silanolate units

S. Spirk, F. Belaj, N. Hurkes and R. Pietschnig, Chem. Commun., 2012, 48, 8398 DOI: 10.1039/C2CC33883A

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