Issue 61, 2012

Lewis base mediated dismutation of trichlorosilane

Abstract

An abnormal N-heterocyclic carbene (aNHC) has been used as a Lewis base to initiate dismutation of trichlorosilane. This report presents the reactivity differences of a normal N-heterocyclic carbene (NHC) versus aNHC with heavier group 14 elements. Three novel compounds (NHC)2·SiCl2H2 (2), aNHC·SiCl2H2 (3), and aNHC·GeCl2 (4) have been synthesized and characterized by single crystal X-ray analysis, solid-state NMR and DFT calculations.

Graphical abstract: Lewis base mediated dismutation of trichlorosilane

Supplementary files

Article information

Article type
Communication
Submitted
26 Apr 2012
Accepted
08 Jun 2012
First published
13 Jun 2012

Chem. Commun., 2012,48, 7574-7576

Lewis base mediated dismutation of trichlorosilane

A. P. Singh, R. S. Ghadwal, H. W. Roesky, J. J. Holstein, B. Dittrich, J. Demers, V. Chevelkov and A. Lange, Chem. Commun., 2012, 48, 7574 DOI: 10.1039/C2CC33835A

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