Issue 61, 2012
From the journal:

Chemical Communications

Gold(i)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination†

Mari C. M. Higginbothama  and  Magnus W. P. Bebbington*a  

* Corresponding authors

a Institute of Chemical Sciences, Heriot-Watt University, Riccarton, Edinburgh, UK
E-mail: m.w.p.bebbington@hw.ac.uk
Fax: +44 (0)131 451 3180
Tel: +44 (0) 131 451 8071

Abstract

Six-membered cyclic sulfamidates are prepared in high yields by treatment of allenic sulfamates with readily available gold(I) complexes. The reaction enables formation of N-substituted quaternary centres and complements existing processes for sulfamidate formation.

Graphical abstract: Gold(i)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination

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Article information

DOI
https://doi.org/10.1039/C2CC33711H
Article type
Communication
Submitted
22 Mar 2012
Accepted
31 May 2012
First published
13 Jun 2012

Chem. Commun., 2012,48, 7565-7567

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Gold(I)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination

M. C. M. Higginbotham and M. W. P. Bebbington, Chem. Commun., 2012, 48, 7565 DOI: 10.1039/C2CC33711H

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