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Issue 63, 2012
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A self-assembled cage as a non-covalent protective group: regioselectivity control in the nucleophilic substitution of aryl-substituted allylic chlorides

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Abstract

Aryl-substituted allylic chlorides are accommodated by a self-assembled cage in such a restricted orientation that the internal reaction sites are shielded while the external ones are exposed. This non-covalent protection enhances terminal regioselectivity in the allylic substitution.

Graphical abstract: A self-assembled cage as a non-covalent protective group: regioselectivity control in the nucleophilic substitution of aryl-substituted allylic chlorides

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Article information


Submitted
22 May 2012
Accepted
19 Jun 2012
First published
19 Jun 2012

Chem. Commun., 2012,48, 7811-7813
Article type
Communication

A self-assembled cage as a non-covalent protective group: regioselectivity control in the nucleophilic substitution of aryl-substituted allylic chlorides

Y. Kohyama, T. Murase and M. Fujita, Chem. Commun., 2012, 48, 7811
DOI: 10.1039/C2CC33660J

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