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Issue 63, 2012
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A self-assembled cage as a non-covalent protective group: regioselectivity control in the nucleophilic substitution of aryl-substituted allylic chlorides

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Abstract

Aryl-substituted allylic chlorides are accommodated by a self-assembled cage in such a restricted orientation that the internal reaction sites are shielded while the external ones are exposed. This non-covalent protection enhances terminal regioselectivity in the allylic substitution.

Graphical abstract: A self-assembled cage as a non-covalent protective group: regioselectivity control in the nucleophilic substitution of aryl-substituted allylic chlorides

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Publication details

The article was received on 22 May 2012, accepted on 19 Jun 2012 and first published on 19 Jun 2012


Article type: Communication
DOI: 10.1039/C2CC33660J
Citation: Chem. Commun., 2012,48, 7811-7813

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    A self-assembled cage as a non-covalent protective group: regioselectivity control in the nucleophilic substitution of aryl-substituted allylic chlorides

    Y. Kohyama, T. Murase and M. Fujita, Chem. Commun., 2012, 48, 7811
    DOI: 10.1039/C2CC33660J

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