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Issue 65, 2012

Dimethylamine borane dehydrogenation chemistry: syntheses, X-ray and neutron diffraction studies of 18-electron aminoborane and 14-electron aminoboryl complexes

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Abstract

The reactions of Me2NH·BH3 with cationic Rh(III) and Ir(III) complexes have been shown to generate the 18-electron aminoborane adduct [Ir(IMes)2(H)22-H2BNMe2)]+ and the remarkable 14-electron aminoboryl complex [Rh(IMes)2(H)-{B(H)NMe2)]+. Neutron diffraction studies have been used for the first time to define H-atom locations in metal complexes of this type formed under catalytic conditions.

Graphical abstract: Dimethylamine borane dehydrogenation chemistry: syntheses, X-ray and neutron diffraction studies of 18-electron aminoborane and 14-electron aminoboryl complexes

Supplementary files

Article information


Submitted
09 May 2012
Accepted
25 Jun 2012
First published
26 Jun 2012

Chem. Commun., 2012,48, 8096-8098
Article type
Communication

Dimethylamine borane dehydrogenation chemistry: syntheses, X-ray and neutron diffraction studies of 18-electron aminoborane and 14-electron aminoboryl complexes

C. Y. Tang, N. Phillips, J. I. Bates, A. L. Thompson, M. J. Gutmann and S. Aldridge, Chem. Commun., 2012, 48, 8096 DOI: 10.1039/C2CC33361A

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