A heteropentanuclear oxalato-bridged [ReIV4GdIII] complex: synthesis, crystal structure and magnetic properties

José Martínez-Lillo; Laura Cañadillas-Delgado; Joan Cano; Francesc Lloret; Miguel Julve; Juan Faus

doi:10.1039/C2CC33350C

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A heteropentanuclear oxalato-bridged [Re^IV₄Gd^III] complex: synthesis, crystal structure and magnetic properties†

José Martínez-Lillo,*^a Laura Cañadillas-Delgado,‡^b Joan Cano,^ac Francesc Lloret,^a Miguel Julve^a and Juan Faus*^a

Author affiliations

* Corresponding authors

^a Departament de Química Inorgánica/Instituto de Ciencia Molecular, Facultat de Química de la Universitat de València, Dr. Moliner 50, Burjassot, Valencia, Spain
E-mail: juan.faus@uv.es, lillo@uv.es

^b Instituto de Ciencia de Materiales de Aragón. CSIC-Universidad de Zaragoza C/ Pedro Cerbuna 12 E-50009 Zaragoza, Spain/Institut Laue Langevin, 6 Rue Jules Horowitz, B.P. 156, 38042 Grenoble, Cedex 9, France

^c Fundació General de la Universitat de València (FGUV), Universitat de València, Valencia, Spain

Abstract

The compound (NBu₄)₅[Gd^III{Re^IVBr₄(μ-ox)}₄(H₂O)]·H₂O (1), with intramolecular antiferromagnetic coupling, is the first Re(IV) system incorporating a 4f ion.

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Article information

DOI: https://doi.org/10.1039/C2CC33350C
Article type: Communication
Submitted: 09 May 2012
Accepted: 24 Jul 2012
First published: 26 Jul 2012

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Chem. Commun., 2012,48, 9242-9244

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A heteropentanuclear oxalato-bridged [Re^IV₄Gd^III] complex: synthesis, crystal structure and magnetic properties

J. Martínez-Lillo, L. Cañadillas-Delgado, J. Cano, F. Lloret, M. Julve and J. Faus, Chem. Commun., 2012, 48, 9242 DOI: 10.1039/C2CC33350C

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