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Issue 62, 2012

Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2([double bond, length as m-dash]GeRR′)]+

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Abstract

Two synthetic routes to cationic ruthenium germylene complexes are described. A hydrogen-substituted germylene complex undergoes various additions of the Ge–H bond to alkene and alkyne substrates.

Graphical abstract: Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2( [[double bond, length as m-dash]] GeRR′)]+

Supplementary files

Article information


Submitted
20 Apr 2012
Accepted
29 May 2012
First published
13 Jun 2012

Chem. Commun., 2012,48, 7690-7692
Article type
Communication

Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2([double bond, length as m-dash]GeRR′)]+

M. E. Fasulo and T. D. Tilley, Chem. Commun., 2012, 48, 7690 DOI: 10.1039/C2CC32840B

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