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Issue 57, 2012
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Beyond click chemistry: spontaneous C-triazolyl transfer from copper to rhenium and transformation into mesoionic C-triazolylidene carbene

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Abstract

The exceptional versatility of the 1,2,3-triazole ring in tridentate carbonyl rhenium complexes has been explored starting from a “click chemistry” unexpected product obtained from the spontaneous copper to rhenium transmetalation, which opens the way to successive transformation to C-triazolyl and triazolylidene mesoionic carbene.

Graphical abstract: Beyond click chemistry: spontaneous C-triazolyl transfer from copper to rhenium and transformation into mesoionic C-triazolylidene carbene

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Article information


Submitted
17 Apr 2012
Accepted
28 May 2012
First published
29 May 2012

Chem. Commun., 2012,48, 7209-7211
Article type
Communication

Beyond click chemistry: spontaneous C-triazolyl transfer from copper to rhenium and transformation into mesoionic C-triazolylidene carbene

C. M. Álvarez, L. A. García-Escudero, R. García-Rodríguez and D. Miguel, Chem. Commun., 2012, 48, 7209
DOI: 10.1039/C2CC32725B

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