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Issue 57, 2012
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Intermediates in the Rh-catalysed dehydrocoupling of phosphine–borane

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Abstract

Active species, product distributions and a suggested catalytic cycle are reported for the dehydrocoupling of the phosphineborane H3B·PtBu2H to give HPtBu2BH2PtBu2BH3 using the [Rh(COD)2][BArF4] pre-catalyst.

Graphical abstract: Intermediates in the Rh-catalysed dehydrocoupling of phosphine–borane

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Article information


Submitted
16 Apr 2012
Accepted
15 May 2012
First published
18 May 2012

Chem. Commun., 2012,48, 7185-7187
Article type
Communication

Intermediates in the Rh-catalysed dehydrocoupling of phosphine–borane

M. A. Huertos and A. S. Weller, Chem. Commun., 2012, 48, 7185
DOI: 10.1039/C2CC32696E

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