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Issue 58, 2012
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Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

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Abstract

Reactions of Cp* substituted pentelidene complexes with the primary phosphine Cp*PH2 yield novel polycyclic phosphorus/arsenic and carbon containing cage compounds via cascade-like reactions. These reactions include a sequence of nucleophilic addition reactions, intramolecular hydrophosphination (partially hydroarsination) reactions, retro-Diels–Alder reactions with Cp*H elimination and subsequent [2+4]-cycloadditions.

Graphical abstract: Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

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Supplementary files

Article information


Submitted
16 Apr 2012
Accepted
30 May 2012
First published
31 May 2012

Chem. Commun., 2012,48, 7262-7264
Article type
Communication

Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

M. Stubenhofer, G. Lassandro, G. Balázs, A. Y. Timoshkin and M. Scheer, Chem. Commun., 2012, 48, 7262 DOI: 10.1039/C2CC32690F

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