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Issue 50, 2012
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Unexpected evolution of optical properties in Ir–Pt complexes upon repeat unit increase: towards an understanding of the photophysical behaviour of organometallic polymers

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Abstract

The photophysical properties of [Ir]-[Pt]-[Ir]-[Pt]-[Ir] ([Ir] = [Ir(ppy)2(bpy*)]+ ([Pt] = trans-Pt(PBu3)2(C[triple bond, length as m-dash]C)2; ppyH = 2-phenylpyridine); bpy* = bipyridyl;) reveal an unprecedented triplet energy transfer from the terminal iridiums to the central Ir subunit.

Graphical abstract: Unexpected evolution of optical properties in Ir–Pt complexes upon repeat unit increase: towards an understanding of the photophysical behaviour of organometallic polymers

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Publication details

The article was received on 06 Apr 2012, accepted on 30 Apr 2012 and first published on 30 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC32492J
Citation: Chem. Commun., 2012,48, 6271-6273
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    Unexpected evolution of optical properties in Ir–Pt complexes upon repeat unit increase: towards an understanding of the photophysical behaviour of organometallic polymers

    A. M. Soliman, D. Fortin, E. Zysman-Colman and P. D. Harvey, Chem. Commun., 2012, 48, 6271
    DOI: 10.1039/C2CC32492J

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